SAFETY DATA SHEET
Issuing Date: 05-Oct-2015 Revision Date: 05-Oct-2015 Version 1
| 1. IDENTIFICATION | |
| Product Name | Dawn Ultra Dishwashing Liquid, Original Scent |
| Product ID: | 97591965_RET_NG |
| Product Type: | Finished Product – Consumer (Retail) Use Only |
| Recommended use | Dish Care |
| Restrictions on Use | Use only as directed on label. |
| Synonyms | Dawn Ultra Dishwashing Liquid, Pomegranate Awakening (97591967_RET_NG) Dawn Ultra Dishwashing Liquid, Apple Orchard Harvest (97591968_RET_NG) |
| Manufacturer | PROCTER & GAMBLE – Fabric and Home Care Division
Ivorydale Technical Centre 5289 Spring Grove Avenue Cincinnati, Ohio 45217-1087 USA Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5 1-800-331-3774 |
| E-mail Address | [email protected] |
| Emergency Telephone | Transportation (24 HR)
CHEMTREC – 1-800-424-9300 (U.S./ Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-9531 |
| 2. HAZARD IDENTIFICATION |
“Consumer Products”, as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the product.
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
| Hazard Category | ||
| Eye Damage / Irritation | Category 2B | |
| Signal Word | WARNING | |
| Hazard Statements | Causes eye irritation | |
| Hazard pictograms | None | |
| Precautionary Statements Prevention
Precautionary Statements Response Precautionary Statements Storage Precautionary Statements Disposal |
Wash hands thoroughly after handling
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Drink 1 or 2 glasses of water None None |
|
| Hazards not otherwise classified (HNOC) | None | |
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
| Chemical Name | Synonyms | Trade Secret | CAS-No | Weight % |
| Sulfuric acid, mono-C10-16-alkyl esters, sodium salts | Sulfuric acid, mono-C10-16-alkyl esters, sodium salts | No | 68585-47-7 | 15 – 20 |
| Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-hydroxy-,
C10-16-alkyl ethers, sodium salts |
Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-hydro
xy-, C10-16-alkyl ethers, sodium salts |
No | 68585-34-2 | 5 – 10 |
| Amine oxides, C10-16-alkyldimethyl | Amine oxides, C10-16-alkyldimethyl | No | 70592-80-2 | 5 – 10 |
| Ethanol | Ethanol | No | 64-17-5 | 1 – 5 |
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.
Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.
Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if symptoms occur.
Inhalation Move to fresh air. If symptoms persist, call a physician.
Most important symptoms/effects, None under normal use conditions. acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
| Suitable extinguishing media | Dry chemical, CO 2, alcohol-resistant foam or water spray. |
| Unsuitable Extinguishing Media | None. |
| Special hazard | None known. |
| Special protective equipment for fire-fighters | As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. |
| Specific hazards arising from the chemical | None. |
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Advice for emergency responders Use personal protective equipment as required.
Methods and materials for containment and cleaning up
| Methods for containment | Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. |
| Methods for cleaning up | Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). |
7. HANDLING AND STORAGE
| Precautions for safe handling | |
| Advice on safe handling | Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children. |
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible products None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines .
| Chemical Name | CAS-No | ACGIH TLV | OSHA PEL | Mexico PEL | |||||
| Ethanol | 64-17-5 | STEL: 1000 ppm | TWA: 1000 ppm
TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 |
Mexico: TWA 1000 ppm Mexico: TWA 1900 mg/m3 | |||||
| Chemical Name | CAS-No | Alberta | Quebec | Ontario TWAEV | British Columbia | ||||
| Ethanol | 64-17-5 | TWA: 1000 ppm TWA: 1880 mg/m3 | TWA: 1000 ppm TWA: 1880 mg/m3 | STEL: 1000 ppm | STEL: 1000 ppm | ||||
No relevant exposure guidelines for other ingredients
Exposure controls
| Engineering Measures
Personal Protective Equipment |
Distribution, Workplace and Household Settings: Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction |
| Eye Protection | Distribution, Workplace and Household Settings: No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Use appropriate eye protection |
| Hand Protection | Distribution, Workplace and Household Settings: No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Protective gloves |
| Skin and Body Protection | Distribution, Workplace and Household Settings: No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY): Wear suitable protective clothing |
| Respiratory Protection | Distribution, Workplace and Household Settings: No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY): In case of insufficient ventilation wear suitable respiratory equipment |
9. PHYSICAL AND CHEMICAL PROPERTIES
| Physical State @20°C | liquid | |||||||||||
| Appearance | Various color by product | |||||||||||
| Odor | Scented | |||||||||||
| Odor threshold | No information available | |||||||||||
| Property pH value
Melting/freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Solubility in other solvents |
Values
9.0 – 9.2 No information available 100 – 104 °C / 212 – 219 °F No Flash to Boiling (NFTB) No information available No information available No information available No information available No information available No information available 1.04 100% No information available |
Note
10% aqueous solution . . |
||||||||||
| Partition coefficient: n-octanol/waterNo information available
Autoignition temperature No information available Decomposition temperature No information available |
||||||||||||
| Viscosity of Product | No information available | |||||||||||
| VOC Content (%) | Products comply with US state and federal regulations for VOC content in consumer products. | |||||||||||
| 10. STABILITY AND REACTIVITY | ||||||||||||
| Reactivity | None under normal use conditions. | |||||||||||
| Stability | Stable under normal conditions. | |||||||||||
| Hazardous polymerization | Hazardous polymerization does not occur. | |||||||||||
| Hazardous Reactions | None under normal processing. | |||||||||||
| Conditions to Avoid | None under normal processing. | |||||||||||
| Materials to avoid | None in particular. | |||||||||||
| Hazardous Decomposition ProductsNone under normal use. | ||||||||||||
| 11. TOXICOLOGICAL INFORMATION | ||||||||||||
| Product Information
Information on likely routes of exposure Inhalation No known effect. |
||||||||||||
| Skin contact | No known effect. | |||||||||||
| Ingestion | No known effect. | |||||||||||
| Eye contact | Irritating to eyes. | |||||||||||
| Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity No known effect. |
||||||||||||
| Skin corrosion/irritation | No known effect. | |||||||||||
| Serious eye damage/eye irritation | Irritating to eyes. | |||||||||||
| Skin sensitization | No known effect. | |||||||||||
| Respiratory sensitization | No known effect. | |||||||||||
| Germ cell mutagenicity | No known effect. | |||||||||||
| Neurological Effects | No known effect. | |||||||||||
| Reproductive toxicity | No known effect. | |||||||||||
| Developmental toxicity | No known effect. | |||||||||||
| Teratogenicity | No known effect. | |||||||||||
| STOT – single exposure | No known effect. | |||||||||||
| STOT – repeated exposure | No known effect. | |||||||||||
| Target Organ Effects | No known effect. | |||||||||||
| Aspiration hazard | No known effect. | |||||||||||
| Carcinogenicity
Component Information |
No known effect. | |||||||||||
| Chemical Name | CAS-No | LD50 Oral | LD50 Dermal | LC50 Inhalation | ||||||||
| Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-hydroxy-,
C10-16-alkyl ethers, sodium salts |
68585-34-2 | >2001 mg/kg | – | – | ||||||||
| 12. ECOLOGICAL INFORMATION | ||||||||||||
Ecotoxicity
The product is not expected to be hazardous to the environment.
Persistence and degradability No information available.
| Bioaccumulative potential | No information available. | |||
| Mobility | No information available. | |||
| Other adverse effects | No information available. | |||
| 13. DISPOSAL CONSIDERATIONS | ||||
| Waste treatment
Waste from Residues / Unused Products |
Disposal should be in accordance with applicable regional, national and local laws and regulations. | |||
| Contaminated packaging | Disposal should be in accordance with applicable regional, national and local laws and regulations. | |||
| California Hazardous Waste Codes (non-household setting) | 331 | |||
| 14. TRANSPORT INFORMATION | ||||
| DOT | Not regulated | |||
| IMDG | Not regulated | |||
| IATA | Not regulated | |||
| 15. REGULATORY INFORMATION | ||||
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
| Chemical Name | CAS-No | Hazardous Substances RQs | Extremely Hazardous Substances RQs | CERCLA/SARA 302 TPQ |
| Sodium hydroxide | 1310-73-2 | 1000 lb | – |
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC’s per the Clean Air Act:
| Chemical Name | CAS-No | CAA (Clean Air Act) – 1990 Hazardous Air Pollutants |
| Phenoxyethanol | 122-99-6 | X |
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):
| Chemical Name | CAS-No | CWA – Reportable Quantities | CWA – Toxic Pollutants | CWA – Priority Pollutants | CWA – Hazardous Substances |
| Sodium hydroxide | 1310-73-2 | 1000 lb | – | – | X |
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
| Chemical Name | CAS-No | New Jersey |
| Ethanol | 64-17-5 | X |
| Chemical Name | CAS-No | Massachusetts |
| Ethanol | 64-17-5 | X |
| Chemical Name | CAS-No | Pennsylvania |
| Ethanol | 64-17-5 | X |
| Sodium hydroxide | 1310-73-2 | X |
| Phenoxyethanol | 122-99-6 | X |
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.
Canada
This product is in compliance with CEPA for import by P&G.
Legend
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
CEPA – Canadian Environmental Protection Act
16. OTHER INFORMATION
Issuing Date: 05-Oct-2015
Revision Date: 05-Oct-2015
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
End of SDS